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oai:docta.ucm.es:20.500.14352/176782024-09-27T14:43:55Zcom_20.500.14352_14col_20.500.14352_15

Stereodivergent-at-Metal Synthesis of [60]Fullerene Hybrids Marco Martínez, Juan Vidal, Sara Fernández López, Israel Filippone, Salvatore Martín, Nazario 547 chiral metallofullerenes · chiral-at-metal complexes · enantioselective synthesis · fullerene chemistry Química orgánica (Química) 2306 Química Orgánica Chiral fullerene–metal hybrids with complete control over the four stereogenic centers, including the absolute configuration of the metal atom, have been synthesized for the first time. The stereochemistry of the four chiral centers formed during [60]fullerene functionalization is the result of both the chiral catalysts employed and the diastereoselective addition of the metal complexes used (iridium, rhodium, or ruthenium).DFT calculations underpin the observed configurational stability at the metal center, which does not undergo an epimerization process. Unión Europea. FP7 Ministerio de Economía y Competitividad (MINECO) Comunidad Autonoma de Madrid Spanish MINECO-FEDER European Research Council (ERC) Depto. de Química Orgánica Fac. de Ciencias Químicas TRUE pub 2023-06-17T21:51:56Z 2023-06-17T21:51:56Z 2017-02-13 journal article https://hdl.handle.net/20.500.14352/17678 1433-7851 10.1002/anie.201611475 eng CHIRALLCARBON (320441) CTQ2014-52045-R PHOTOCARBON (S2013/MIT-2841) (Grants CTQ2013-44303-P and CTQ2014-51912-REDC) open access application/pdf Wiley Online Library