2026-06-08T03:26:29Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/231782023-07-18T05:06:46Zcom_20.500.14352_14col_20.500.14352_15

Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry Ramos, Soriano Reina, José J. Pérez, Sánchez Illescas, Beatriz M. Rojo, Javier Martín, Nazario 547 Química orgánica (Química) 2306 Química Orgánica The synthesis of a new highly symmetric hexakis adduct of C60 appended with 12 cyclooctyne moieties has been carried out. This compound has been used for the copper-free strain-promoted cycloaddition reaction to a series of azides with excellent yields.This strategy for the obtention of clicked adducts of [60]fullerene is of special interest for biological applications. Unión Europea. FP7 Ministerio de Economía y Competitividad (MINECO) Comunidad de Madrid European Research Council (ERC) Depto. de Química Orgánica Fac. de Ciencias Químicas TRUE pub 2023-06-18T05:43:45Z 2023-06-18T05:43:45Z 2016-07 journal article https://hdl.handle.net/20.500.14352/23178 1359-7345 10.1039/c6cc05484f eng CHIRALLCARBON (320441) (CTQ2014-52045-R and CTQ2014-52328- P) PHOTOCARBON (S2013/MIT-2841) open access application/pdf RSC