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00925njm 22002777a 4500 dc Cenarro, A. J. author Cardiel López, Nicolás author Vazdekis, A. author Gorgas García, Francisco Javier author 2009-07-11 Using the near-infrared spectral stellar library of Cenarro et al., the behaviour of the Mg i line at 8807 A and nearby TiO bands is analyzed in terms of the effective temperature, surface gravity and metallicity of the library stars. New spectroscopic indices for both spectral features - namely MgI and sTiO - are defined, and their sensitivities to different signal-to-noise ratios, spectral resolutions, flux calibrations and sky emission-line residuals are characterized. The two new indices exhibit interesting properties. In particular, MgI is a good indicator of the Mg abundance, whereas sTiO is a powerful dwarf-to-giant discriminator for cold spectral types. Empirical fitting polynomials that reproduce the strength of the new indices as a function of the stellar atmospheric parameters are computed, and a fortran routine with the fitting function predictions is made available. A thorough study of several error sources, non-solar [Mg/Fe] ratios and their influence on the fitting function residuals is also presented. From this analysis, an [Mg/Fe] underabundance of similar to -0.04 is derived for the Galactic open cluster M67. 0035-8711 10.1111/j.1365-2966.2009.14839.x https://hdl.handle.net/20.500.14352/44452 http://dx.doi.org/10.1111/j.1365-2966.2009.14839.x http://mnras.oxfordjournals.org/ Mg and TiO spectral features at the near-IR: spectrophotometric index definitions and empirical calibrations