2026-08-20T06:02:16Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/528352023-08-27T15:39:40Zcom_20.500.14352_14col_20.500.14352_15

A short and convenient procedure for the stereoselective synthesis of 2-hydroxy-1-norbornanesulfonamides Garcı́a Martı́nez, Antonio Teso Vilar, Enrique Moreno Jiménez, Florencio Álvarez Garcı́a, Ana Mª A short and convenient procedure for the stereoselective synthesis of novel optically active 2-hydroxy-1-norbornanesulfonamides starting from commercially available natural camphor and fenchone is reported. The synthetic route involves a nucleophilic substitution at the sulfenyl sulfur atom of 2-methylene-1-norbornylthiotriflates followed by oxidation of the intermediate sulfenamides and highly diastereoselective reduction of the carbonyl group of the parent 2-oxo-1-norbornanesulfonamides. 2023-06-20T12:56:00Z 2023-06-20T12:56:00Z 2023-06-20T12:56:00Z 2004-01-26 journal article https://hdl.handle.net/20.500.14352/52835 0957-4166 10.1016/j.tetasy.2003.10.023 eng BQU(2001-1347-C02-02) 2001V/PROYT/18 restricted access Elsevier Ltd.