2026-06-27T13:59:16Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/581692023-08-28T14:56:28Zcom_20.500.14352_14col_20.500.14352_15

Garcı́a Martı́nez, Antonio Teso Vilar, Enrique Moreno Jiménez, Florencio Garcı́a Amo, María 2023-06-20T17:22:44Z 2023-06-20T17:22:44Z 2000-05-05 0957-4166 10.1016/S0957-4166(00)00122-1 https://hdl.handle.net/20.500.14352/58169 https://doi.org/10.1016/S0957-4166(00)00122-1 New homochiral 1-norbornanesulfenic and sulfonic acid derivatives 2–7, as well as the sulfonic acids 8, are easily synthesised starting from 2-methylene-1-norbornylthiotriflates 1. This new class of homochiral bridgehead thiosulfonates was prepared by us from naturally occurring (+)-camphor and (−)-fenchone. Nucleophilic substitution at the sulfenyl sulfur atom is the key step for this synthetic strategy eng restricted access Enantiospecific synthesis of substituted 1-norbornanesulfonic acids and 1-norbornanesulfenic and sulfonic acid derivatives journal article