2026-06-27T15:15:41Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/76372024-06-24T13:56:04Zcom_20.500.14352_14col_20.500.14352_15

00925njm 22002777a 4500 dc López Quintas, Ignacio author Rebollar, Esther author Ávila Brande, David author Izquierdo, Jesús G. author Díaz-Guerra Viejo, Carlos author Urbieta Quiroga, Ana Irene author Castillejo, Marta author Nalda, Rebeca de author Martín Fernández, Margarita author 2020-11 Nanostructured thin films of Co-doped zinc sulfide were synthesized through femtosecond pulsed laser deposition. The scheme involved ablation of physically mixed Co and ZnS with pairs of ultrashort pulses separated in time in the 0-300 ps range. In situ monitorization of the deposition process was carried out through a simultaneous reflectivity measurement. The crystallinity of generated nanoparticles and the inclusion of Co in the ZnS lattice is demonstrated by transmission electron microscopy and energy dispersive X-ray microanalysis (TEM-EDX) characterization. Surface morphology, Raman response, and photoluminescence of the films have also been assessed. The role of interpulse temporal separation is most visible in the thickness of the films obtained at the same total fluence, with much thicker films deposited with short delays than with individual uncoupled pulses. The proportion of Co in the synthesized doped ZnS nanoparticles is found to be substantially lower than the original proportion, and practically independent on interpulse delay. 2079-4991 10.3390/nano10112229 https://hdl.handle.net/20.500.14352/7637 http://dx.doi.org/10.3390/nano10112229 https://www.mdpi.com/2079-4991/10/11/2229 Femtosecond double-pulse laser ablation and deposition of Co-doped ZnS thin films