2026-06-08T11:03:07Zhttps://docta.ucm.es/rest/oai/requestoai:docta.ucm.es:20.500.14352/82482023-08-28T07:19:32Zcom_20.500.14352_14col_20.500.14352_15
Docta Complutense
author
Prior, David
author
Cortijo Montes, Miguel
author
González Prieto, Rodrigo
author
Herrero Domínguez, Santiago
author
Jiménez Aparicio, Reyes
author
Perles Hernáez, Josefina
author
Priego Bermejo, José Luis
2023-06-17T09:08:09Z
2023-06-17T09:08:09Z
2019-11-23
2073-4352
10.3390/cryst9120614
https://hdl.handle.net/20.500.14352/8248
https://doi.org/10.3390/cryst9120614
https://www.mdpi.com/2073-4352/9/12/614
In this article, we describe the preparation of anionic heteronuclear one-dimensional coordination polymers made by dirhodium paddlewheels and tetracyanido-metallatate building blocks. A series of complexes of (PPh4)2n[{Rh2(µ-O2CCH3)4}{M(CN)4}]n (M = Ni (1), Pd (2), Pt (3)) formulae were obtained by reaction of [Rh2(μ-O2CCH3)4] with (PPh4)2[M(CN)4] in a 1:1 or 2:1 ratio. Crystals of 1−3 suitable for single crystal X-ray diffraction were grown by slow diffusion of a dichloromethane solution of the dirhodium complex into a chloroform solution of the corresponding tetracyanido–metallatate salt. Compounds 1 and 2 are isostructural and crystallize in the triclinic P-1 space group, while compound 3 crystallizes in the monoclinic P21/n space group. A detailed description of the structures is presented, including the analysis of the packing of anionic chains and PPh4+ cations.
eng
Atribución 3.0 España
Linear One-Dimensional Coordination Polymers Constructed by Dirhodium Paddlewheel and Tetracyanido-Metallate Building Blocks
journal article
URL
https://docta.ucm.es/bitstreams/265c6b8f-9d43-4ed4-bf8d-aad7443f99a2/download
File
MD5
ffbe16fb0a5ca0c55a196b9427b6228f
1007095
application/pdf
crystals-09-00614-v2.pdf