2026-06-08T01:19:12Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/82482023-08-28T07:19:32Zcom_20.500.14352_14col_20.500.14352_15

Linear One-Dimensional Coordination Polymers Constructed by Dirhodium Paddlewheel and Tetracyanido-Metallate Building Blocks Prior, David Cortijo Montes, Miguel González Prieto, Rodrigo Herrero Domínguez, Santiago Jiménez Aparicio, Reyes Perles Hernáez, Josefina Priego Bermejo, José Luis dirhodium compounds tetracyanido-metallatate complexes one-dimensional coordination polymers Química inorgánica (Química) 2303 Química Inorgánica In this article, we describe the preparation of anionic heteronuclear one-dimensional coordination polymers made by dirhodium paddlewheels and tetracyanido-metallatate building blocks. A series of complexes of (PPh4)2n[{Rh2(µ-O2CCH3)4}{M(CN)4}]n (M = Ni (1), Pd (2), Pt (3)) formulae were obtained by reaction of [Rh2(μ-O2CCH3)4] with (PPh4)2[M(CN)4] in a 1:1 or 2:1 ratio. Crystals of 1−3 suitable for single crystal X-ray diffraction were grown by slow diffusion of a dichloromethane solution of the dirhodium complex into a chloroform solution of the corresponding tetracyanido–metallatate salt. Compounds 1 and 2 are isostructural and crystallize in the triclinic P-1 space group, while compound 3 crystallizes in the monoclinic P21/n space group. A detailed description of the structures is presented, including the analysis of the packing of anionic chains and PPh4+ cations. Ministerio de Economía y Competitividad (MINECO) Comunidad de Madrid Depto. de Química Inorgánica Fac. de Ciencias Químicas TRUE pub 2023-06-17T09:08:09Z 2023-06-17T09:08:09Z 2019-11-23 journal article https://hdl.handle.net/20.500.14352/8248 2073-4352 10.3390/cryst9120614 eng CTQ2015-63858-P RyPSE-CM (B2017/BMD-3770) Atribución 3.0 España https://creativecommons.org/licenses/by/3.0/es/ open access application/pdf MDPI