2026-06-08T01:04:14Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/82482023-08-28T07:19:32Zcom_20.500.14352_14col_20.500.14352_15

Linear One-Dimensional Coordination Polymers Constructed by Dirhodium Paddlewheel and Tetracyanido-Metallate Building Blocks Prior, David Cortijo Montes, Miguel González Prieto, Rodrigo Herrero Domínguez, Santiago Jiménez Aparicio, Reyes Perles Hernáez, Josefina Priego Bermejo, José Luis In this article, we describe the preparation of anionic heteronuclear one-dimensional coordination polymers made by dirhodium paddlewheels and tetracyanido-metallatate building blocks. A series of complexes of (PPh4)2n[{Rh2(µ-O2CCH3)4}{M(CN)4}]n (M = Ni (1), Pd (2), Pt (3)) formulae were obtained by reaction of [Rh2(μ-O2CCH3)4] with (PPh4)2[M(CN)4] in a 1:1 or 2:1 ratio. Crystals of 1−3 suitable for single crystal X-ray diffraction were grown by slow diffusion of a dichloromethane solution of the dirhodium complex into a chloroform solution of the corresponding tetracyanido–metallatate salt. Compounds 1 and 2 are isostructural and crystallize in the triclinic P-1 space group, while compound 3 crystallizes in the monoclinic P21/n space group. A detailed description of the structures is presented, including the analysis of the packing of anionic chains and PPh4+ cations. 2023-06-17T09:08:09Z 2023-06-17T09:08:09Z 2023-06-17T09:08:09Z 2019-11-23 journal article https://hdl.handle.net/20.500.14352/8248 2073-4352 10.3390/cryst9120614 eng CTQ2015-63858-P RyPSE-CM (B2017/BMD-3770) https://creativecommons.org/licenses/by/3.0/es/ open access Atribución 3.0 España MDPI