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oai:docta.ucm.es:20.500.14352/82772024-09-02T15:35:12Zcom_20.500.14352_14col_20.500.14352_15

Cyclic olefin polymer as a novel membrane material for membrane distillation applications Sabzekar, M. Chenar, M. Pourafshari;, M. Pourafshari Maghsoud, Z. Mostaghisi, O. García Payo, M. Carmen Khayet Souhaimi, Mohamed 536 Hollow-fiber membranes Flat-sheet membranes Phase inversion membranes Self-sustained webs Waste-water Experimental-design Vacuum membrane Mass-transport Separation Pvdf Termodinámica 2213 Termodinámica The authors gratefully acknowledge the financial support of the Spanish Ministry of Economy and Competitiveness through its project CTM2015-65348-C2-2-R, the Spanish Ministry of Science, Innovation and Universities through its project RTI2018-096042-B-C22 and also Sarkhoon and Qeshm Gas Refinery Company of Iran (No. 266270). A first attempt was made to prepare cyclic olefin polymer/copolymer (COP/COC) flat-sheet porous membranes by the well-known non-solvent induced phase separation method. In this study, two solvents (chloroform and 1,2,4-trichlorobenzene), different additives (polyvinylpyrrolidone, PVP, polyethylene glycol, PEG400, polyethylene oxide, PEO, and Sorbitan monooleate, Span 80) and coagulants (acetone and 70/30 wt% acetone/water mixture) were employed. The prepared membranes were characterized in terms of the thickness (70-85 mu m), porosity (-50-80%), liquid entry pressure (1.16-4.55 bar), water contact angle (similar to 86 degrees - 111 degrees), mean pore size (158-265 nm), mechanical properties (tensile strength: 0.74-5.51 MPa, elongation at break: 3.34%-7.94% and Young's modulus: 29-237 MPa), morphological and topographical characteristics. Short-term direct contact membrane distillation (DCMD) tests showed maximum permeate fluxes of 20 kg m(-2) h(-1) and 15 kg m(-2) h(-1) when using as feed distilled water and 30 g/L sodium chloride aqueous solution, respectively, with a high salt separation factor (99.99%). Long-term DCMD tests of some selected membranes carried out during 24-50 h showed that the membranes prepared with PEG additive exhibited more stable DCMD performance. In general, it was proved that COP can be successfully used as a novel polymer candidate in membrane distillation (MD) applications. Ministerio de Economía y Competitividad (MINECO) Ministerio de Ciencia e Innovación (MICINN) Sarkhoon and Qeshm Gas Refinery Company of Iran Depto. de Estructura de la Materia, Física Térmica y Electrónica Fac. de Ciencias Físicas TRUE pub 2023-06-17T09:08:57Z 2023-06-17T09:08:57Z 2021-03-01 journal article https://hdl.handle.net/20.500.14352/8277 0376-7388 10.1016/j.memsci.2020.118845 eng CTM2015-65348-C2-2-R RTI2018-096042-B-C22 266270 open access application/pdf Elsevier B. V.