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00925njm 22002777a 4500 dc Toledano Pinedo, Mireia author Anatóliev, Hristo author Martínez Del Campo, Teresa author Almendros, Pedro author 2019-11-14 We report herein a study on the Ag/Cu-catalyzed reactivity of α-allenols. The focus was the development of new methodologies for cyclization and/or transposition of this moiety. By simple solvent switch, the divergent preparation of dihydrofurans and 3-halo-3-alkenals in a controlled manner has been reached. 2504-3900 10.3390/ecsoc-23-06467 https://hdl.handle.net/20.500.14352/8288 https://doi.org/10.3390/ecsoc-23-06467 https://www.mdpi.com/2504-3900/41/1/58 Solvent-Controlled Switching of Cycloisomerization to Transposition in the Ag/Cu-Promoted Reaction of Terminal α-Allenols