2026-07-24T20:54:06Zhttps://docta.ucm.es/rest/oai/requestoai:docta.ucm.es:20.500.14352/86632025-09-15T13:33:05Zcom_20.500.14352_14col_20.500.14352_15
Docta Complutense
author
Ray Leiva, César
author
Schad, Christopher
author
Moreno Jiménez, Florencio
author
Maroto, Beatriz Lora
author
Bañuelos Prieto, Jorge
author
Arbeloa, Teresa
author
García Moreno, Inmaculada
author
Villafuerte, Cassie
author
Muller, Gilles
author
Moya Cerero, Santiago de la
2023-06-17T09:21:59Z
2023-06-17T09:21:59Z
2020
Ray C, Schad C, Moreno F, Maroto BL, Bañuelos J, Arbeloa T, García-Moreno I, Villafuerte C, Muller G, De La Moya S. BCl3 -Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions. J Org Chem 2020; 85: 4594–4601. [DOI: 10.1021/acs.joc.9b03059]
0022-3263
10.1021/acs.joc.9b03059
https://hdl.handle.net/20.500.14352/8663
https://dx.doi.org/10.1021/acs.joc.9b03059
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7272132/https://www.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pubmed&retmode=ref&cmd=prlinks&id=32138513
A general and straightforward method for the synthesis of COO-BODIPYs from F-BODIPYs and carboxylic acids is established. The method is based on the use of boron trichloride to activate the involved substitution of fluorine, which leads to high yields through rapid reactions under soft conditions. This mild method opens the way to unprecedented laser dyes with outstanding efficiencies and photostabilities, which are difficult to obtain by the current methods.
eng
BCl3‑Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions
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