2026-06-08T01:05:13Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/918092024-07-23T23:48:32Zcom_20.500.14352_14col_20.500.14352_15

00925njm 22002777a 4500 dc Yang, Yizhou author Chen, Yanyan author Izquierdo Ruiz, Fernando author Schäfer, Clara author Rahm, Martin author Börjesson, Karl author 2023 Abstract Covalent crystals such as diamonds are a class of fascinating materials that are challenging to fabricate in the form of thin films. This is because spatial kinetic control of bond formation is required to create covalently bonded crystal films. Directional crystal growth is commonly achieved by chemical vapor deposition, an approach that is hampered by technical complexity and associated high cost. Here we report on a liquid-liquid interfacial approach based on physical-organic considerations to synthesize an ultrathin covalent crystal film. By distributing reactants into separate phases using hydrophobicity, the chemical reaction is confined to an interface that orients the crystal growth. A molecular-smooth interface combined with in-plane isotropic conditions enables the synthesis of films on a centimeter size scale with a uniform thickness of 13 nm. The film exhibits considerable mechanical robustness enabling a free-standing length of 37 µm, as well as a clearly anisotropic chemical structure and crystal lattice alignment. Yang, Y., Chen, Y., Izquierdo-Ruiz, F. et al. A self-standing three-dimensional covalent organic framework film. Nat Commun 14, 220 (2023). https://doi.org/10.1038/s41467-023-35931-4 2041-1723 10.1038/s41467-023-35931-4 https://hdl.handle.net/20.500.14352/91809 https://doi.org/10.1038/s41467-023-35931-4 A self-standing three-dimensional covalent organic framework film