2026-06-28T14:58:28Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/918282024-07-24T00:06:50Zcom_20.500.14352_14col_20.500.14352_15

Synthesis of polycyclic aromatic hydrocarbons decorated by fluorinated carbon acids/carbanions Hoshikawa, Shoki Yanai, Hikaru Martín‐Mejías, Irene Lázaro Milla, Carlos Aragoncillo Abanades, Cristina Almendros Requena, Pedro Matsumoto, Takashi The carboarylation reaction of biphenyl‐alkynes was successfully triggered by electrophilic attack of 1,1‐bis(triflyl)ethylene on the alkyne moiety to give polycyclic aromatic hydrocarbons (PAHs) decorated by superacidic carbon acid functionality. Neutralisation of thus obtained acids with NaHCO3 yielded the corresponding sodium salts, which showed improved solubility in both aqueous and organic solvents. 2024-01-08T14:21:40Z 2024-01-08T14:21:40Z 2024-01-08T14:21:40Z 2021 journal article https://hdl.handle.net/20.500.14352/91828 0947-6539 10.1002/chem.202103188 1521-3765 eng Hoshikawa S, Yanai H, Martín-Mejías I, Lázaro-Milla C, Aragoncillo C, Almendros P, Matsumoto T. Synthesis of Polycyclic Aromatic Hydrocarbons Decorated by Fluorinated Carbon Acids/Carbanions, 2021, 27, 16112-16116. restricted access Wiley-VCH GmbH