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Martín, Irene Aragoncillo Abanades, Cristina Almendros Requena, Pedro 2024-01-09T09:16:50Z 2024-01-09T09:16:50Z 2021 Martín-Mejías I, Aragoncillo C, Almendros P. Palladium-Catalyzed Hydroarylation of Homopropargyl Iodoindoles with Concurrent Alkyl and Iodonium Migrations. Adv. Synth. Catal. 2021, 363, 1449-1456. 1615-4150 10.1002/adsc.202001267 https://hdl.handle.net/20.500.14352/91934 1615-4169 https://doi.org/10.1002/adsc.202001267 A selective palladium‐catalyzed C-arylation/carbocyclization/iodonium migration reaction sequence has been accomplished. Novel 2‐iodo‐1‐aryl‐9-H‐carbazoles are now easily available. As this result is contrary to the selectivity observed using gold catalysis, the formation of 2‐iodocarbazoles is noticeable, suggesting a metal‐controlled cyclization through chemo‐ and regioselective 1,2‐alkyl migration and 1,4‐iodonium migration. eng restricted access Palladium‐catalyzed hydroarylation of homopropargyl iodoindoles with concurrent alkyl and iodonium migrations journal article