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Platinum and Gold Catalysis: à la Carte Hydroamination of Terminal Activated Allenes with Azoles Alonso Gómez, José Miguel Muñoz, María Paz 547 Química orgánica (Química) 2306 Química Orgánica Nucleophilic additions to allenes catalyzed by transition metals represent a powerful tool to obtain selective access to diverse structures with numerous applications. Reported here is a straightforward methodology to achieve selective addition of azoles to the proximal or distal carbon of activated allenes depending on the catalyst used, unravelling a gold–platinum bimetallic catalysis approach for the 1,3-double addition of azoles to activated allenes to give 1,3-bisazole derivatives, an important scaffold in medicinal and organometallic chemistry. University of East Anglia (Reino Unido) The Leverhulme Trust (Reino Unido) Depto. de Química Orgánica Fac. de Ciencias Químicas TRUE pub 2024-01-11T10:20:10Z 2024-01-11T10:20:10Z 2019 journal article VoR https://hdl.handle.net/20.500.14352/92460 1523-7060 10.1021/acs.orglett.9b02949 1523-7052 eng Alonso, José Miguel, y María Paz Muñoz. «Platinum and Gold Catalysis: À La Carte Hydroamination of Terminal Activated Allenes with Azoles». Organic Letters, vol. 21, n.o 18, septiembre de 2019, pp. 7639-44. https://doi.org/10.1021/acs.orglett.9b02949. restricted access application/pdf American Chemical Society