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Matern, Jonas Dorca, Yeray Sánchez Martín, Luis Fernández, Gustavo 2024-01-15T15:13:14Z 2024-01-15T15:13:14Z 2019 Matern, J.; Dorca, Y.; Sánchez, L.; Fernández, G. Revising Complex Supramolecular Polymerization under Kinetic and Thermodynamic Control. Angew. Chem. Int. Ed. 2019, 58, 16730-16740 DOI:10.1002/anie.201905724. 1433-7851 10.1002/anie.201905724 https://hdl.handle.net/20.500.14352/93154 1521-3773 https://doi.org/10.1002/anie.201905724 Abstract Pathway complexity, hierarchical organization, out of equilibrium, and metastable or kinetically trapped species are common terms widely used in recent, high‐quality publications in the field of supramolecular polymers. Often, the terminologies used to describe the different self‐assembly pathways, the species involved, as well as their relationship and relative stability are not trivial. Different terms and classifications are commonly found in the literature, however, in many cases, without clear definitions or guidelines on how to use them and how to determine them experimentally. The aim of this Minireview is to classify, differentiate, and correlate the existing concepts with the help of recent literature reports to provide the reader with a general insight into thermodynamic and kinetic aspects of complex supramolecular polymerization processes. A good comprehension of these terms and concepts should contribute to the development of new complex, functional materials. eng http://creativecommons.org/licenses/by-nc-nd/4.0/ open access Attribution-NonCommercial-NoDerivatives 4.0 International Revising complex supramolecular polymerization under kinetic and thermodynamic control journal article