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Influence of chromium content on the optical and electrical properties of Li1+xCrxTi2-x(PO4)3 Pérez Estébanez, Marta Isasi Marín, Josefa Díaz-Guerra Viejo, Carlos Rivera Calzada, Alberto Carlos León Yebra, Carlos Santamaría Sánchez-Barriga, Jacobo 54 Ionic transport Lithium ionic conductors Solid electrolytes Lithium batteries Química 23 Química Optical and electrical properties of samples with Li1 + xCrxTi2 − x(PO4)3 composition (x = 0, 0.05 and 0.1) prepared by a low temperature sol-gel method have been investigated. XRD and Raman spectroscopy measurements respectively reveal the rhombohedral-Nasicon structure of the grown samples and a disorder of Li+ ions with increasing chromium content. Electrical properties were studied by impedance spectroscopy and both dc and grain boundary ionic conductivity increase with Cr content. A high ionic conductivity value of 1.4·10−4 S cm−1 at room temperature and an activation energy of 0.31 eV have been obtained for x = 0.1, which are comparable to those measured in the best ionic conductors reported to date. Photoluminescence and cathodoluminescence spectra indicate that self-trapped excitons and oxygen defects related to the TiO6 octahedra structural units are responsible for the observed luminescence in the visible spectral range, explaining the possible electronic origin of a residual conductivity measured in all the samples. Cr incorporation gives rise to infrared emission bands, attributed to different Cr3+ and Ti3+ intraionic transitions, that may be related to the better grain connectivity achieved by Cr doping. Ministerio de Ciencia, Innovación y Universidades (España) Universidad Complutense de Madrid Depto. de Pintura y Conservación-Restauración Depto. de Física de Materiales Fac. de Bellas Artes Fac. de Ciencias Físicas TRUE pub 2024-01-19T13:52:49Z 2024-01-19T13:52:49Z 2013 journal article VoR https://hdl.handle.net/20.500.14352/94092 0167-2738 10.1016/j.ssi.2013.04.001 eng Pérez-Estébanez, M., et al. «Influence of Chromium Content on the Optical and Electrical Properties of Li1+xCrxTi2−x(PO4)3». Solid State Ionics, vol. 241, junio de 2013, pp. 36-45. https://doi.org/10.1016/j.ssi.2013.04.001. restricted access application/pdf Elsevier