2026-08-20T02:04:23Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/984742025-08-27T17:46:25Zcom_20.500.14352_14col_20.500.14352_15

Arnanz, Avelina González-Arellano, Camino Juan, Alberto Villaverde Cantizano, Gonzalo Corma, Avelino Iglesias, Marta Sánchez, Félix 2024-02-02T17:30:08Z 2024-02-02T17:30:08Z 2010 Arnanz, Avelina, et al. «New Chiral Ligands Bearing Two N-Heterocyclic Carbene Moieties at a Dioxolane Backbone. Gold, Palladium and Rhodium Complexes as Enantioselective Catalysts». Chemical Communications, vol. 46, n.o 17, abril de 2010, pp. 3001-03. pubs.rsc.org, https://doi.org/10.1039/B922534J. 1359-7345 10.1039/b922534j https://hdl.handle.net/20.500.14352/98474 1364-548X https://www.doi.org/10.1039/b922534j https://pubs.rsc.org/en/content/articlelanding/2010/cc/b922534j Biscarbene ligands with two imidazolin-2-ylidene moieties at a chiral dioxolane backbone were used as ligands for gold, rhodium and palladium complexes. All new complexes showed varying degrees of enantioselectivity toward hydrogenation of prochiral alkenes with ees up to 95%. eng open access New chiral ligands bearing two N-heterocyclic carbene moieties at a dioxolane backbone. Gold, palladium and rhodium complexes as enantioselective catalysts journal article