2026-06-29T08:18:39Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/988952024-12-10T00:55:03Zcom_20.500.14352_14col_20.500.14352_15

Negishi reaction in BODIPY dyes. Unprecedented alkylation by palladium-catalyzed C–C coupling in boron dipyrromethene derivatives Durán Sampedro, Gonzalo Palao, Eduardo Rodríguez Agarrabeitia, Antonia Moya Cerero, Santiago de la Boens, Noël Ortiz García, María Josefa 547 Photophysycal properties Energy-transfer Fluorescence Química orgánica (Química) 22 Física 23 Química 33 Ciencias Tecnológicas Negishi reactions of 3-halogen and 3,5-dihalogen substituted BODIPYs with different organozinc reagents are reported as the first examples of this valuable palladium-catalyzed C–C coupling reaction into the family of the BODIPY dyes. It is demonstrated that the Negishi coupling is especially useful for obtaining interesting alkylated BODIPYs, including synthetically-valuable asymmetrically-3,5-disubstituted BODIPYs. Ministerio de Economía, Comercio y Empresa (España) Depto. de Química Orgánica Fac. de Ciencias Químicas TRUE pub 2024-02-05T12:07:14Z 2024-02-05T12:07:14Z 2014 journal article VoR https://hdl.handle.net/20.500.14352/98895 2046-2069 10.1039/c4ra00651h eng info:eu-repo/grantAgreement/MICINN//MAT2010-20646-C04-02/ES/DISEÑO, SINTESIS Y CARACTERIZACION DE NUEVOS COLORANTES ORGANICOS CON EMISION EN LA REGION ESPECTRAL DEL AZUL, ROJO E IR CERCANO, PARA APLICACIONES AVANZADAS/ Durán Sampedro, G., Palao, E., Rodríguez Agarrabeitia, A. et al. «Negishi Reaction in BODIPY Dyes. Unprecedented Alkylation by Palladium-Catalyzed C–C Coupling in Boron Dipyrromethene Derivatives». RSC Adv., vol. 4, n.o 37, 2014, pp. 19210-13. https://doi.org/10.1039/C4RA00651H. restricted access application/pdf Royal Society of Chemistry