San Martin, DanielMartínez Del Campo, TeresaAlmendros, P.2025-07-302025-07-302025-02-1910.1002/adsc.202500080https://hdl.handle.net/20.500.14352/122891We report the direct and selective synthesis of oxadendralenes starting from readily available bis(α-hydroxyallenes). The designed sequence involves a hitherto unknown oxy-Cope rearrangement of allenols by supplying a site for the migration of the 1,2-diene moiety. Moreover, the so-prepared oxadendralenes were converted into valuable polyfunctionalized scaffolds through effective late-stage diversification.engAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/journal articlehttps://doi.org/10.1002/adsc.202500080open access547Química orgánica (Química)2306 Química Orgánica