García Melo, FátimaAparicio, FátimaMarenchino, MarcoCampos-Olivas, RamónSánchez Martín, Luis2024-01-232024-01-232010Fátima García, Fátima Aparicio, Marco Marenchino, Ramón Campos-Olivas, and Luis Sánchez Organic Letters 2010 12 (19), 4264-4267 DOI: 10.1021/ol101673z4264-426710.1021/ol101673zhttps://hdl.handle.net/20.500.14352/94885The synthesis of two chiral amphiphiles and their self-assembling features in solution and onto surfaces is reported. The different degree of interdigitation of the paraffinic substituents has an enormous influence in the chirality of the aggregates. Thus, while oligo(phenylene ethynylene) 1 shows a bisignated Cotton effect in solution and P-type helices onto surfaces, compound 2 lacks in any dichroic response at room temperature and self-assembles into flat ribbons.engHelical and Flat Structures from Chiral Dendronized Rectangular Oligo(phenylene ethynylene)sjournal articlehttps://doi.org/10.1021/ol101673zrestricted access54Ciencias23 Química