Villaverde Cantizano, GonzaloArnanz, AvelinaIglesias, MartaMonge, ÁngelesSánchez, FélixSnejko, Natalia2024-02-022024-02-022011Villaverde, Gonzalo, et al. «Development of Homogeneous and Heterogenized Rhodium(i) and Palladium(Ii) Complexes with Ligands Based on a Chiral Proton Sponge Building Block and Their Application as Catalysts». Dalton Transactions, vol. 40, n.o 37, 2011, p. 9589. https://doi.org/10.1039/c1dt10597c.1477-922610.1039/c1dt10597chttps://hdl.handle.net/20.500.14352/98475Chiral compounds prepared from proton sponge building block 8-((2R,5R)-2,5-dimethylpyrrolidin-1-yl)naphthalen-1-amine were found to be effective chiral ligands for obtaining complexes of rhodium(I) and palladium(II) by reaction with [RhCl(cod)]2, PdCl2(cod) or Pd(OAc)2. The complexes bearing triethoxysilane groups were immobilized on mesoporous MCM-41 in order to obtain new heterogeneous catalysts. Both materials are active in the hydrogenation of alkenes and could be recycled without loss of activity or enantioselectivity.engjournal article1477-9234https://doi.org/10.1039/c1dt10597chttps://pubs.rsc.org/en/content/articlelanding/2011/dt/c1dt10597cmetadata only accessQuímica23 Química