Corrales Castellanos, Maria EugeniaLoriot, VincentBalerdi Villanueva, GarikoitzGonzález Vázquez, JesúsNalda Míguez, Rebeca deBañares Morcillo, LuisZewail, Ahmed2024-01-312024-01-312014Corrales, María E., et al. «Structural Dynamics Effects on the Ultrafast Chemical Bond Cleavage of a Photodissociation Reaction». Physical Chemistry Chemical Physics, vol. 16, n.o 19, 2014, p. 8812. https://doi.org/10.1039/c3cp54677b.1463-907610.1039/c3cp54677bhttps://hdl.handle.net/20.500.14352/96874The correlation between chemical structure and dynamics has been explored in a series of molecules with increasing structural complexity in order to investigate its influence on bond cleavage reaction times in a photodissociation event. Femtosecond time-resolved velocity map imaging spectroscopy reveals specificity of the ultrafast carbon–iodine (C–I) bond breakage for a series of linear (unbranched) and branched alkyl iodides, due to the interplay between the pure reaction coordinate and the rest of the degrees of freedom associated with the molecular structure details. Full-dimension time-resolved dynamics calculations support the experimental evidence and provide insight into the structure–dynamics relationship to understand structural control on time-resolved reactivityengAttribution-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nd/4.0/Structural dynamics effects on the ultrafast chemical bond cleavage of a photodissociation reactionjournal article1463-9084https://doi.org/10.1039/c3cp54677brestricted access544HydrocarbonsHalogenatedMolecular Dynamics SimulationMolecular StructurePhotochemical ProcessesTime FactorsQuímica física (Química)2307 Química Física