Roscales García, SilviaGarcía Csaky, Aurelio2025-01-272025-01-272015Roscales, Silvia, y Aurelio G. Csákÿ. «Transition-Metal-Free Direct Anti -Carboboration of Alkynes with Boronic Acids To Produce Alkenylheteroarenes». Organic Letters, vol. 17, n.o 6, marzo de 2015, pp. 1605-08. DOI.org (Crossref), https://doi.org/10.1021/acs.orglett.5b00517.10.1021/acs.orglett.5b00517https://hdl.handle.net/20.500.14352/116175The transition-metal-free intermolecular direct 1,2-carboboration reaction of heteroarylacetylenes using boronic acids as reagents is achieved by utilizing tartaric acid as promoter. The reaction proceeds with excellent regioselectivity and anti stereoselectivity to afford boroxole frameworks. The resulting compounds are of use for the stereoselective preparation of polysubstituted alkenylheteroarenes.engTransition-Metal-Free Direct anti-Carboboration of Alkynes with Boronic Acids To Produce Alkenylheteroarenesjournal articlehttps://doi.org/10.1021/acs.orglett.5b00517restricted access547Química orgánica (Química)2306 Química Orgánica