Reaction of diazocompounds with C70: unprecedented synthesis and characterization of isomeric [5,6]-fulleroids†

Vidal, SaraIzquierdo, MartaFilippone, SalvatoreBrunetti, Fulvio G.Martín, Nazario2023-06-192023-06-1920151364-548x(Online) , 1359-7345 (print)10.1039/c5cc07602ahttps://hdl.handle.net/20.500.14352/35071The synthesis of a variety of PCBM-type [5,6]-fulleroids and their further highly selective photoisomerization to the respective [6,6]-methanofullerenes is presented. Interestingly, the chemical reactivity of [5,6]-fulleroids reveals the same trend (a 4 b 4 c 4 d) to that observed for pristine C70 (a 4 b 4 c 4 d).engReaction of diazocompounds with C70: unprecedented synthesis and characterization of isomeric [5,6]-fulleroids†journal articlehttp://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc07602aopen access547isomerizationsynthesisQuímica orgánica (Química)2306 Química Orgánica