Atienza Castellanos, Carmen MaríaSánchez Martín, Luis2024-04-032024-04-032024-03-25Chem. Eur. J. 20240947-65391521-376510.1002/chem.202400379https://hdl.handle.net/20.500.14352/102623Different approaches to achieve 2D supramolecular polymers, as an alternative to the covalent bottom‐up approaches reported for the preparation of 2D materials, are reviewed. The significance of the operation of weak non‐covalent forces to induce a lateral growth of a number of self‐assembling units is collected. The examples of both thermodynamically and kinetically controlled formation of 2D supramolecular polymers showed in this review demonstrate the utility of this strategy to achieve new 2D materials with biased morphologies (nanosheets, scrolls, porous surfaces) and showing elegant applications like chiral recognition, enantioselective uptake or asymmetric organic transformations. Furthermore, elaborated techniques like seeded or living supramolecular polymerizations have been demonstrated to give rise to complex 2D nanostructures.engAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/journal articlehttps://doi.org/10.1002/chem.202400379open access547Química orgánica (Química)2306 Química Orgánica