Cano Rico, IsraelGómez-Bengoa, EnriqueLanda, AitorMaestro, MiguelMielgo, AntoniaOlaizola, IurreOiarbide, MikelPalomo, Claudio2024-01-172024-01-172012I. Cano, E. Gómez-Bengoa, A. Landa, M. Maestro, A. Mielgo, I. Olaizola, M. Oiarbide, C. Palomo. N-(Diazoacetyl)oxazolidin-2-thiones as sulfur donor reagents: Asymmetric synthesis of thiiranes from aldehydes. Angew. Chem., Int. Ed. 2012, 51, 10856-108601433-785110.1002/anie.201204771https://hdl.handle.net/20.500.14352/93578We reported the first Rh-catalyzed reaction of a diazoacetyl compound with aldehydes that affords thiiranes, instead of oxiranes, as known before. This unusual reactivity relied on the use of N-(diazoacetyl)oxazolidin-2-thiones as new chiral sulfur-donor reagents and enabled the direct production of optically active thiiranes with very high stereoselectivity.engjournal article1521-3773https://doi.org/10.1002/anie.201204771open access546Química inorgánica (Química)2303 Química Inorgánica