Transition metal-free cyclobutene rearrangement in fused naphthalen-1-ones: controlled access to functionalized quinones

Luna Costales, AmparoHerrera García, FernandoAlmendros Requena, PedroFernández López, Israel2025-01-102025-01-102019-12-19Herrera Fernando, Luna Amparo, Fernández Israel, Almendros Pedro. Transition metal-free cyclobutene rearrangement in fused naphthalen-1-ones: controlled access to functionalized quinones. Chem. Commun., 2020, 56 (8), 1290-12931359-734510.1039/C9CC08628Ehttps://hdl.handle.net/20.500.14352/113815The controlled synthesis of 1,4-naphthoquinones and tetraphene7,12-diones, which bear the ABCD-ring of landomycins, has been accomplished directly through oxidative rearrangement of common stable precursors, namely, previously non-isolable cyclobuta[a]naphthalen4(2H)-ones.engAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/Transition metal-free cyclobutene rearrangement in fused naphthalen-1-ones: controlled access to functionalized quinonesjournal article1364-548Xhttps://pubs.rsc.org/en/content/articlelanding/2020/cc/c9cc08628e31904044https://digital.csic.es/handle/10261/209781https://pubmed.ncbi.nlm.nih.gov/31904044/open access547quinone1,4-naphthoquinonesallenynolsQuímica orgánica (Química)2306 Química Orgánica2306.10 Compuestos Heterocíclicos