Prior, DavidCortijo Montes, MiguelGonzález Prieto, RodrigoHerrero Domínguez, SantiagoJiménez Aparicio, ReyesPerles Hernáez, JosefinaPriego Bermejo, José Luis2023-06-172023-06-172019-11-232073-435210.3390/cryst9120614https://hdl.handle.net/20.500.14352/8248In this article, we describe the preparation of anionic heteronuclear one-dimensional coordination polymers made by dirhodium paddlewheels and tetracyanido-metallatate building blocks. A series of complexes of (PPh4)2n[{Rh2(µ-O2CCH3)4}{M(CN)4}]n (M = Ni (1), Pd (2), Pt (3)) formulae were obtained by reaction of [Rh2(μ-O2CCH3)4] with (PPh4)2[M(CN)4] in a 1:1 or 2:1 ratio. Crystals of 1−3 suitable for single crystal X-ray diffraction were grown by slow diffusion of a dichloromethane solution of the dirhodium complex into a chloroform solution of the corresponding tetracyanido–metallatate salt. Compounds 1 and 2 are isostructural and crystallize in the triclinic P-1 space group, while compound 3 crystallizes in the monoclinic P21/n space group. A detailed description of the structures is presented, including the analysis of the packing of anionic chains and PPh4+ cations.engAtribución 3.0 Españajournal articlehttps://doi.org/10.3390/cryst9120614https://www.mdpi.com/2073-4352/9/12/614open accessdirhodium compoundstetracyanido-metallatate complexesone-dimensional coordination polymersQuímica inorgánica (Química)2303 Química Inorgánica