García Arroyo, PalomaMartínez Periñán, EmilianoCabreraTrujillo, Jorge J.Salagre, ElenaMichel, Enrique G.Martínez, José I.Lorenzo, EncarnaciónSegura Castedo, José Luis2025-09-172025-09-172022-06-14García-Arroyo, P., Martínez-Periñán, E., Cabrera-Trujillo, J.J. et al. Pyrenetetraone-based covalent organic framework as an effective electrocatalyst for oxygen reduction reaction. Nano Res. 15, 3907–3912 (2022). https://doi.org/10.1007/s12274-021-4043-210.1007/s12274-021-4043-2https://hdl.handle.net/20.500.14352/124042A novel porous and crystalline two dimensional (2D) electrochemically active covalent organic framework (COF) based on ortho-quinone units has been prepared as an innovative approach towards the development of organic cathode materials with multiple redox sites as efficient electrocatalyst for the oxygen reduction reaction (ORR). In contrast with most of the previously reported COFs as electrocatalysts for the ORR, the electrocatalytic application of this material toward ORR has been investigated without adding any metal or conductive supporting material and avoiding any additional carbonization step. Additionally, the electrochemical properties of the COF material have been compared with two analogue amorphous frameworks with similar chemical composition, which points out the important role of the enhanced crystallinity and porosity of the COF network in its superior performance as electrocatalysts towards ORR.engjournal articlehttps://doi.org//10.1007/s12274-021-4043-2https://link.springer.com/article/10.1007/s12274-021-4043-2embargoed access547ElectrocatalysisOxygen reduction reactionMetal freePyrenetetraoneCovalent organic frameworkCiencias23 Química