Nirmalraj, PeterDaly, RonanMartín, NazarioThompson, Damien2023-06-172023-06-172017-021944-8252 (Online) 1944-8244(Print)10.1021/acsami.7b00408.https://hdl.handle.net/20.500.14352/17660Research on motion of molecules in the presence of thermal noise is central for progress in two-terminal molecular scale electronic devices. However, it is still unclear what influence imperfections in bottom metal electrode surface can have on molecular motion. Here, we report a two-layer crowding study, detailing the early stages of surface motion of fullerene molecules on Au(111) with nanoscale pores in a n-tetradecane chemical environment. The motion of the fullerenes is directed by crowding of the underlying n-tetradecane molecules around the pore fringes at the liquid−solid interface. We observe in real-space the growth of molecular populations around different pore geometries. Supported by atomic-scale modeling, our findings extend the established picture of molecular crowding by revealing that trapped solvent molecules serve as prime nucleation sites at nanopore fringes.engjournal articlehttp://pubs.acs.org/doi/abs/10.1021/acsami.7b00408restricted access547Molecular dynamicsnanoporesfullerenesscanning tunneling microscopy and spectroscopyQuímica orgánica (Química)2306 Química Orgánica