García, D.Herranz, M.AngelesRodríguez Pérez, LauraPeña, D.Guitián, E.Bailey, S.Al-Galiby, Q.Noori, M.Lambert, C.J.Pérez, D.Martín, Nazario2023-06-182023-06-1820161359-7345 (Print)1364-548X(Online)10.1039/c5cc10462ahttps://hdl.handle.net/20.500.14352/23486The synthesis of a [60]fullerene‐benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all‐carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the formation of both [2+2] and [4+2] cycloadducts on the graphene surface is feasible.engjournal articlehttp://pubs.rsc.org/en/content/articlepdf/2016/cc/c5cc10462aopen access547Química orgánica (Química)2306 Química Orgánica