Hoshikawa, ShokiYanai, HikaruMartín‐Mejías, IreneLázaro Milla, CarlosAragoncillo Abanades, CristinaAlmendros Requena, PedroMatsumoto, Takashi2024-01-082024-01-082021Hoshikawa S, Yanai H, Martín-Mejías I, Lázaro-Milla C, Aragoncillo C, Almendros P, Matsumoto T. Synthesis of Polycyclic Aromatic Hydrocarbons Decorated by Fluorinated Carbon Acids/Carbanions, 2021, 27, 16112-16116.0947-653910.1002/chem.202103188https://hdl.handle.net/20.500.14352/91828The carboarylation reaction of biphenyl‐alkynes was successfully triggered by electrophilic attack of 1,1‐bis(triflyl)ethylene on the alkyne moiety to give polycyclic aromatic hydrocarbons (PAHs) decorated by superacidic carbon acid functionality. Neutralisation of thus obtained acids with NaHCO3 yielded the corresponding sodium salts, which showed improved solubility in both aqueous and organic solvents.engSynthesis of polycyclic aromatic hydrocarbons decorated by fluorinated carbon acids/carbanionsjournal article1521-3765https://doi.org/10.1002/chem.202103188restricted access547PolycyclicAromaticFluorinatedQuímica orgánica (Química)2306 Química Orgánica2306.02 Hidrocarburos Aromáticos