Roscales García, SilviaGarcía Csaky, Aurelio2025-10-312025-10-312018-03-01Synthesis of Di(hetero)arylamines from Nitrosoarenes and Boronic Acids: A General, Mild, and Transition-Metal-Free Coupling Silvia Roscales and Aurelio G. Csákÿ Organic Letters 2018 20 (6), 1667-1671 DOI: 10.1021/acs.orglett.8b0047310.1021/acs.orglett.8b00473https://hdl.handle.net/20.500.14352/125553The synthesis of di(hetero)arylamines by a transition-metal-free cross-coupling between nitrosoarenes and boronic acids is reported. The procedure is experimentally simple, fast, mild, and scalable and has a wide functional group tolerance, including carbonyls, nitro, halogens, free OH and NHgroups. It also permits the synthesis of sterically hindered compounds.engAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/journal articlehttps://pubs.acs.org/doi/10.1021/acs.orglett.8b00473metadata only access547Química orgánica (Química)2306 Química Orgánica