Medina Rivero, SamaGarcía Arroyo, PalomaLi, LiangGunasekaran, SumanStuyver, ThijsMancheño Real, María JoséAlonso, MercedesVenkataraman, LathaSegura Castedo, José LuisCasado, Juan2026-01-152026-01-152021Samara Medina Rivero, Paloma García Arroyo, Liang Li, Suman Gunasekaran, Thijs Stuyver, María José Mancheño, Mercedes Alonso, Latha Venkataraman, José L. Segura and Juan Casado. Single-molecule conductance in a unique cross-conjugated tetra(aminoaryl)ethene. Chem. Commun., 2021, 57, 59110.1039/d0cc07124b rsc.li/chemcommhttps://hdl.handle.net/20.500.14352/130318A 1,1,2,2-tetrakis(4-aminophenyl)ethene with three paths of π-conjugation, linear-cis, linear-trans and a cross-conjugation, has been prepared. The molecule is able to bind to gold electrodes forming molecular junctions for single-molecule conductance measurements. Only two regimes of conduction are found experimentally. The modelling of the conductance allows to assign them to through-bond transmission in the linear case, while the cross-conjugated channel is further assisted by through-space transmission, partially alleviating the destructive quantum interference.engjournal articlehttps://doi.org/10.1039/D0CC07124Bhttps://pubs.rsc.org/en/content/articlelanding/2021/cc/d0cc07124brestricted access547Ciencias23 Química