Person:
Moreno Jiménez, Florencio

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First Name
Florencio
Last Name
Moreno Jiménez
URI
https://hdl.handle.net/20.500.14352/79918
Affiliation
Universidad Complutense de Madrid
Faculty / Institute
Óptica y Optometría
Department
Química Orgánica
Area
Química Orgánica
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2002 - 20042
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Author: Garcı́a Martı́nez, Antonio × Subject: 547.1 ×

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Now showing 1 - 2 of 2
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    A novel and simple procedure for the enantiospecific synthesis of bridgehead norbornane thioethers and thiocyanates
    (Tetrahedron: Asymmetry, 2002) Garcı́a Martı́nez, Antonio; Teso Vilar, Enrique; Moreno Jiménez, Florencio; Álvarez García, Ana María; Pinilla Rodríguez, Patricia
    An easy three-step route for the enantiospecific synthesis of novel 1-norbornyl thioethers and thiocyanates from readily available natural fenchone and camphor is described. The key step of the synthetic route is the nucleophilic substitution over the sulfenyl sulfur atom of the intermediate thiotriflates by the corresponding C-nucleophiles.
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    A short and convenient procedure for the stereoselective synthesis of 2-hydroxy-1-norbornanesulfonamides
    (Tetrahedron: Asymmetry, 2004) Garcı́a Martı́nez, Antonio; Teso Vilar, Enrique; Moreno Jiménez, Florencio; Álvarez Garcı́a, Ana Mª
    A short and convenient procedure for the stereoselective synthesis of novel optically active 2-hydroxy-1-norbornanesulfonamides starting from commercially available natural camphor and fenchone is reported. The synthetic route involves a nucleophilic substitution at the sulfenyl sulfur atom of 2-methylene-1-norbornylthiotriflates followed by oxidation of the intermediate sulfenamides and highly diastereoselective reduction of the carbonyl group of the parent 2-oxo-1-norbornanesulfonamides.