Person:
Moreno Jiménez, Florencio

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First Name
Florencio
Last Name
Moreno Jiménez
URI
https://hdl.handle.net/20.500.14352/79918
Affiliation
Universidad Complutense de Madrid
Faculty / Institute
Óptica y Optometría
Department
Química Orgánica
Area
Química Orgánica
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2015 - 201932020 - 20211
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Author: Moreno Jiménez, Florencio × Subject: 535.37 ×

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Now showing 1 - 4 of 4
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    Circularly Polarized Luminescence from Simple Organic Molecules
    (Chemistry: a european journal, 2015) Márquez Sánchez-Carnerero, Esther María; Rodríguez Agarrabeitia, Antonia; Moreno Jiménez, Florencio; Lora Maroto, Beatriz; Muller, Gilles; Ortiz García, María Josefa; Moya Cerero, Santiago De La
    This article aims to show the identity of “circularly polarized luminescent active simple organic molecules” as a new concept in organic chemistry due to the potential interest of these molecules, as availed by the exponentially growing number of research articles related to them. In particular, it describes and highlights the interest and difficulty in developing chiral simple (small and non-aggregated) organic molecules able to emit left- or right-circularly polarized light efficiently, the efforts realized up to now to reach this challenging objective, and the most significant milestones achieved to date. General guidelines for the preparation of these interesting molecules are also presented.
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    BINOLated aminostyryl BODIPYs: a workable organic molecular platform for NIR circularly polarized luminescence
    (Chemical Communications, 2021) Jiménez González, Josué; Díaz Norambuena, Carolina; Serrano Villar, Sergio; Ma, Shing Cho; Moreno Jiménez, Florencio; Maroto, Beatriz Lora; Bañuelos Prieto, Jorge; Muller, Gilles; Moya Cerero, Santiago De La
    The accessible at-boron-BINOLated 3,5-bis(4-aminostyryl)ated BODIPY scaffold is highlighted as a workable platform for developing enantiopure small organic molecules exhibiting CPL in the NIR region, even in water solution, the latter being key for CPL-based bioapplications. Synthetic simplicity, noticeable chiroptical efficiency in the NIR and the possibility to access water-soluble emitters pave the way for advancing CPL tools based on organic emitters and NI radiation.
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    Modulating ICT emission: a new strategy to manipulate the CPL sign in chiral emitters
    (Chemical Communications, 2019) Jiménez González, Josué; Moreno Jiménez, Florencio; Maroto, Beatriz Lora; Cabreros, Trevor A.; Huy, Angelenia S.; Muller, Gilles; Bañuelos Prieto, Jorge; Moya Cerero, Santiago De La
    A new strategy to manipulate the circularly polarized luminescence (CPL) handedness in chiral emitters, based on modulating the population of an emissive ICT state, is proposed. Such a strategy is particularly interesting for conformationally rigid and non-aggregating chiral organic emitters, opening up new perspectives for the development of CPL application based on organic molecules
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    Bis(haloBODIPYs) with Labile Helicity: Valuable Simple Organic Molecules That Enable Circularly Polarized Luminescence
    (Chemistry: a european journal, 2016) Ray Leiva, César; Márquez Sánchez-Carnerero, Esther María; Moreno Jiménez, Florencio; Lora Maroto, Beatriz; Rodríguez Agarrabeitia, Antonia; Ortiz García, María Josefa; López Arbeloa, Íñigo María; Bañuelos Prieto, Jorge; Cohovi, Komlan D.; Lunkley, jamie L.; Muller, Gilles; Moya Cerero, Santiago De La
    Simple organic molecules (SOM) based on bis(haloBODIPY) are shown to enable circularly polarized luminescence (CPL), giving rise to a new structural design for technologically valuable CPL-SOMs. The established design comprises together synthetic accessibility, labile helicity, possibility of reversing the handedness of the circularly polarized emission, and reactive functional groups, making it unique and attractive as advantageous platform for the development of smart CPL-SOMs.