Person:
Marggi Poullaín, Sonia

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First Name
Sonia
Last Name
Marggi Poullaín
URI
https://hdl.handle.net/20.500.14352/76279
Affiliation
Universidad Complutense de Madrid
Faculty / Institute
Ciencias Químicas
Department
Química Física
Area
Química Física
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2017 - 20192
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Author: Corrales, Maria Eugenia ×

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Now showing 1 - 2 of 2
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    Femtosecond predissociation dynamics of ethyl iodide in the B-band
    (Physical Chemistry Chemical Physics, 2019) Murillo Sánchez, Marta Luisa; Marggi Poullaín, Sonia; Loriot, Vincent; Corrales, Maria Eugenia; Bañares Morcillo, Luis
    Femtosecond velocity map imaging to disentangle the electronic predissociation of ethyl iodide in the B-band.
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    Femtosecond photodissociation dynamics of chloroiodomethane in the first absorption band
    (Chemical Physics Letters, 2017) Murillo Sánchez, Marta Luisa; Marggi Poullaín, Sonia; González-Vázquez, Jesús; Corrales, Maria Eugenia; Balerdi, Garikoitz; Bañares Morcillo, Luis
    The real time photodissociation of chloroiodomethane (CH2ICl) in the first absorption band at 268 nm is reported in comparison with the well-known methyl iodide (CH3I) in order to investigate the halogen-atom substituent effect on the time-resolved photodynamics of halomethanes. Femtosecond velocity map imaging measurements in conjunction with resonance enhanced multiphoton ionization (REMPI) to detect the iodine fragments have been performed to obtain translational energy, angular distributions and the photodissociation reaction times. High level ab initio and on-the-fly trajectory calculations have been carried out to rationalize the experimental results in terms of the excited states involved and the dissociation mechanisms.