Person:
López Cabarcos, Enrique

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First Name
Enrique
Last Name
López Cabarcos
Affiliation
Universidad Complutense de Madrid
Faculty / Institute
Farmacia
Department
Química en Ciencias Farmacéuticas
Area
Química Física
Identifiers
UCM identifierORCIDScopus Author IDWeb of Science ResearcherIDDialnet IDGoogle Scholar ID

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  • Publication
    FRET distance dependence from upconverting nanoparticles to quantum dots
    (Amer Chemical Soc, 2018-05) Melle Hernández, Sonia; Gómez Calderón, Óscar; Laurenti, Marco; Méndez González, Diego; Egatz-Gómez, Ana; López Cabarcos, Enrique; Cabrera Granado, Eduardo; Díaz García, Elena; Rubio Retama, Jorge
    Förster resonant energy transfer (FRET) with upconverting nanoparticles (UCNPs) as donors and quantum dots (QDs) as acceptors has been regarded as a promising tool for biosensing applications. In this work, we use time-resolved fluorescence spectroscopy to analyze the UCNP-to-QD FRET and we focus on the most relevant parameter of the FRET phenomenon, UCNP-QD distance. This distance is controlled by a nanometric silica shell around the UCNP surface. We theoretically reproduce the experimental results applying FRET theory to the distribution of emitting erbium ions in the UCNP. This simple model allows us to estimate the contribution of every erbium ion to the final FRET response and to explore different strategies to improve FRET efficiency.