Person:
Cano Rico, Israel

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First Name
Israel
Last Name
Cano Rico
URI
https://hdl.handle.net/20.500.14352/86450
Affiliation
Universidad Complutense de Madrid
Faculty / Institute
Ciencias Químicas
Department
Química Inorgánica
Area
Química Inorgánica
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End date: 2017 × Subject: 546 ×

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    N-(Diazoacetyl)oxazolidin-2-thiones as Sulfur-Donor Reagents: Asymmetric Synthesis of Thiiranes from Aldehydes
    (2012) Cano Rico, Israel; Gómez-Bengoa, Enrique; Landa, Aitor; Maestro, Miguel; Mielgo, Antonia; Olaizola, Iurre; Oiarbide, Mikel; Palomo, Claudio
    We reported the first Rh-catalyzed reaction of a diazoacetyl compound with aldehydes that affords thiiranes, instead of oxiranes, as known before. This unusual reactivity relied on the use of N-(diazoacetyl)oxazolidin-2-thiones as new chiral sulfur-donor reagents and enabled the direct production of optically active thiiranes with very high stereoselectivity.