Person:
García Csaky, Aurelio

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First Name
Aurelio
Last Name
García Csaky
URI
https://hdl.handle.net/20.500.14352/76165
Affiliation
Universidad Complutense de Madrid
Faculty / Institute
Ciencias Químicas
Department
Química Orgánica
Area
Química Orgánica
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Start date: 2018 × Subject: 544.2 ×

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    (Ph3P)AuCl-catalyzed homocoupling of arylboronic acids under benchtop conditions: Synthesis of biphenyls
    (Molecular Catalysis, 2023) Roscales García, Silvia; Sánchez-Sancho, Francisco; García Csaky, Aurelio
    (Ph3P)AuCl was discovered to be a powerful catalyst in the homocoupling of arylboronic acids and potassium aryltrifluoroborates for the synthesis of symmetrical biaryls. The reactions take place under benchtop reaction conditions in 96% EtOH at temperatures between rt and 50 °C with no exclusion of air or humidity, in the presence of F-TEDA (Selectfluor™) as an oxidant. The procedure is very functional group tolerant, and affords the corresponding biaryls in high yields with large substrate scope (26 examples).