Person:
Roscales García, Silvia

First Name

Silvia

Last Name

Roscales García

URI

https://hdl.handle.net/20.500.14352/74087

Affiliation

Universidad Complutense de Madrid

Identifiers

Full item page

Search Results

Now showing 1 - 2 of 2

Nuevos aspectos de las reacciones de los ácidos borónicos: de la catálisis metálica a la catálisis orgánica
(2015) Roscales García, Silvia; García Csáky, Aurelio
(Ph3P)AuCl-catalyzed homocoupling of arylboronic acids under benchtop conditions: Synthesis of biphenyls
(Molecular Catalysis, 2023) Roscales García, Silvia; Sánchez-Sancho, Francisco; García Csaky, Aurelio
(Ph3P)AuCl was discovered to be a powerful catalyst in the homocoupling of arylboronic acids and potassium aryltrifluoroborates for the synthesis of symmetrical biaryls. The reactions take place under benchtop reaction conditions in 96% EtOH at temperatures between rt and 50 °C with no exclusion of air or humidity, in the presence of F-TEDA (Selectfluor™) as an oxidant. The procedure is very functional group tolerant, and affords the corresponding biaryls in high yields with large substrate scope (26 examples).

Person:
Roscales García, Silvia

First Name

Last Name

URI

Affiliation

Faculty / Institute

Department

Area

Identifiers

Filters

Author

Subject

Date

Has files

Item Type

Settings

Sort By

Results per page

Search Results

Person: Roscales García, Silvia

First Name

Last Name

URI

Affiliation

Faculty / Institute

Department

Area

Identifiers

Filters

Author

Subject

Date

Has files

Item Type

Settings

Sort By

Results per page

Search Results

Person:
Roscales García, Silvia