Graphene grown on transition metal substrates: Versatile templates for organic molecules with new properties and structures

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dc.contributor.authorDíaz Blanco, Cristina
dc.contributor.authorCalleja, Fabián
dc.contributor.authorVázquez de Parga, Amadeo L.
dc.contributor.authorMartín, Fernando
dc.date.accessioned2023-06-22T12:33:20Z
dc.date.available2023-06-22T12:33:20Z
dc.date.issued2022-09-18
dc.descriptionCRUE-CSIC (Acuerdos Transformativos 2022)
dc.description.abstractThe interest in graphene (a carbon monolayer) adsorbed on metal surfaces goes back to the 60’s, long before isolated graphene was produced in the laboratory. Owing to the carbon-metal interaction and the lattice mismatch between the carbon monolayer and the metal surface, graphene usually adopts a rippled structure, known as moir´e, that confers it interesting electronic properties not present in isolated graphene. These moir´e structures can be used as versatile templates where to adsorb, isolate and assemble organic-molecule structures with some desired geometric and electronic properties. In this review, we first describe the main experimental techniques and the theoretical methods currently available to produce and characterize these complex systems. Then, we review the diversity of moir´e structures that have been reported in the literature and the consequences for the electronic properties of graphene, attending to the magnitude of the lattice mismatch and the type of interaction, chemical or physical, between graphene and the metal surface. Subsequently, we address the problem of the adsorption of single organic molecules and then of several ones, from dimers to complete monolayers, describing both the different arrangements that these molecules can adopt as well as their physical and chemical properties. We pay a special attention to graphene/Ru(0001) due to its exceptional electronic properties, which have been used to induce long-range magnetic order in tetracyanoquinodimethane (TCNQ) monolayers, to catalyze the (reversible) reaction between acetonitrile and TCNQ molecules and to efficiently photogenerate large acenes.en
dc.description.departmentDepto. de Química Física
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia, Innovación y Universidades (España)
dc.description.sponsorshipCentro de Excelencia Severo Ochoa
dc.description.sponsorshipUnidad de Excelencia María de Maeztu
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/76048
dc.identifier.citationDíaz, C.; Calleja, F.; Vázquez de Parga, A. L.; Martín, F. Graphene grown on transition metal substrates: Versatile templates for organic molecules with new properties and structures. Surface Science Reports 2022, 77, 100575 DOI:10.1016/j.surfrep.2022.100575.
dc.identifier.doi10.1016/j.surfrep.2022.100575
dc.identifier.issn01675729
dc.identifier.officialurlhttps://doi.org/10.1016/j.surfrep.2022.100575
dc.identifier.relatedurlhttps://www.sciencedirect.com/science/article/pii/S0167572922000243?via%3Dihub
dc.identifier.urihttps://hdl.handle.net/20.500.14352/72819
dc.issue.number4
dc.journal.titleSurface Science Reports
dc.language.isoeng
dc.page.initial100575
dc.publisherElsevier
dc.relation.projectIDPID2019- 105458RB-I00, PID2019-106732GB-I00 and PGC2018-093291-B-I00.
dc.relation.projectID(CEX2020- 001039-S)
dc.relation.projectID(CEX2018-000805-M)
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.cdu544
dc.subject.keywordGraphene on metals
dc.subject.keywordOrganic molecules
dc.subject.keywordGeometrical properties
dc.subject.keywordElectronic properties
dc.subject.ucmQuímica física (Química)
dc.subject.ucmCiencias
dc.subject.unesco22 Física
dc.titleGraphene grown on transition metal substrates: Versatile templates for organic molecules with new properties and structuresen
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number77
dspace.entity.typePublication
relation.isAuthorOfPublication340a9e67-3487-41f5-a6e1-fbd2be739b26
relation.isAuthorOfPublication.latestForDiscovery340a9e67-3487-41f5-a6e1-fbd2be739b26
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