Publication:
Growth of β-LiNaSO4 and Li2SO4 . H20: epitaxy and intergrowth phenomena

dc.contributor.authorPina Martínez, Carlos Manuel
dc.contributor.authorFernández Díaz, Lurdes
dc.contributor.authorLópez García, José Ángel
dc.contributor.authorPrieto Rubio, Manuel
dc.date.accessioned2023-06-20T16:49:04Z
dc.date.available2023-06-20T16:49:04Z
dc.date.issued1995
dc.description.abstractIsothermal crystallization in the system Na2SO4-Li2SO4-H20 was carried out at 50°C by "salting out" in a tetrametoxysilane (TMS) gel medium. Under these conditions the solid phases that can crystallize are Na2SO4, Li2SO4 . H20 and β-LiNaSO4, depending on the initial composition of the gel interstitial solution. When the initial [Na2SO4]/[Li2SO4] molar ratio in the interstitial solution is smaller than 1, first β-LiNaSO4 crystallizes and, subsequently, Li2SO4 • H20. The nucleation of Li2SO4 • H20 is always heterogeneous and occurs epitaxially on the surface of β-LiNaSO4 crystals. Occasionally, successive heterogenous nucleation events promote the development of intergrowth phenomena. In this paper a detailed study of both epitactic growth and crystal morphology is worked out. Finally, the observed epitaxial relationships are interpreted on the ground of structural considerations.
dc.description.departmentDepto. de Mineralogía y Petrología
dc.description.facultyFac. de Ciencias Geológicas
dc.description.refereedTRUE
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/14055
dc.identifier.doiSSDI 0022-0248(94)00963-5
dc.identifier.issn0022-0248
dc.identifier.officialurlhttp://www.journals.elsevier.com/journal-of-crystal-growth/
dc.identifier.urihttps://hdl.handle.net/20.500.14352/57120
dc.journal.titleJournal of Crystal Growth
dc.language.isoeng
dc.page.final288
dc.page.initial283
dc.publisherElsevier Science B.V.
dc.rights.accessRightsopen access
dc.subject.cdu548.5
dc.subject.keywordCrystal Growth
dc.subject.keywordIsotermal crystallization
dc.subject.ucmCristalografía (Geología)
dc.titleGrowth of β-LiNaSO4 and Li2SO4 . H20: epitaxy and intergrowth phenomena
dc.typejournal article
dc.volume.number148
dspace.entity.typePublication
relation.isAuthorOfPublicationea4a455d-94c9-4139-ba99-fbc6fea3e899
relation.isAuthorOfPublication31641195-dfe4-43a9-af29-174b4bae8ca5
relation.isAuthorOfPublication.latestForDiscoveryea4a455d-94c9-4139-ba99-fbc6fea3e899
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