Growth of β-LiNaSO4 and Li2SO4 . H20: epitaxy and intergrowth phenomena
| dc.contributor.author | Pina Martínez, Carlos Manuel | |
| dc.contributor.author | Fernández Díaz, María Lourdes | |
| dc.contributor.author | López García, José Ángel | |
| dc.contributor.author | Prieto Rubio, Manuel | |
| dc.date.accessioned | 2023-06-20T16:49:04Z | |
| dc.date.available | 2023-06-20T16:49:04Z | |
| dc.date.issued | 1995 | |
| dc.description.abstract | Isothermal crystallization in the system Na2SO4-Li2SO4-H20 was carried out at 50°C by "salting out" in a tetrametoxysilane (TMS) gel medium. Under these conditions the solid phases that can crystallize are Na2SO4, Li2SO4 . H20 and β-LiNaSO4, depending on the initial composition of the gel interstitial solution. When the initial [Na2SO4]/[Li2SO4] molar ratio in the interstitial solution is smaller than 1, first β-LiNaSO4 crystallizes and, subsequently, Li2SO4 • H20. The nucleation of Li2SO4 • H20 is always heterogeneous and occurs epitaxially on the surface of β-LiNaSO4 crystals. Occasionally, successive heterogenous nucleation events promote the development of intergrowth phenomena. In this paper a detailed study of both epitactic growth and crystal morphology is worked out. Finally, the observed epitaxial relationships are interpreted on the ground of structural considerations. | |
| dc.description.department | Depto. de Mineralogía y Petrología | |
| dc.description.faculty | Fac. de Ciencias Geológicas | |
| dc.description.refereed | TRUE | |
| dc.description.status | pub | |
| dc.eprint.id | https://eprints.ucm.es/id/eprint/14055 | |
| dc.identifier.doi | SSDI 0022-0248(94)00963-5 | |
| dc.identifier.issn | 0022-0248 | |
| dc.identifier.officialurl | http://www.journals.elsevier.com/journal-of-crystal-growth/ | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14352/57120 | |
| dc.journal.title | Journal of Crystal Growth | |
| dc.language.iso | eng | |
| dc.page.final | 288 | |
| dc.page.initial | 283 | |
| dc.publisher | Elsevier Science B.V. | |
| dc.rights.accessRights | open access | |
| dc.subject.cdu | 548.5 | |
| dc.subject.keyword | Crystal Growth | |
| dc.subject.keyword | Isotermal crystallization | |
| dc.subject.ucm | Cristalografía (Geología) | |
| dc.title | Growth of β-LiNaSO4 and Li2SO4 . H20: epitaxy and intergrowth phenomena | |
| dc.type | journal article | |
| dc.volume.number | 148 | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | ea4a455d-94c9-4139-ba99-fbc6fea3e899 | |
| relation.isAuthorOfPublication | 5283531a-5de9-4e87-bcc7-1c218b2d3a89 | |
| relation.isAuthorOfPublication | 31641195-dfe4-43a9-af29-174b4bae8ca5 | |
| relation.isAuthorOfPublication.latestForDiscovery | ea4a455d-94c9-4139-ba99-fbc6fea3e899 |
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