On the Significance of the Anchoring Group in the Design of Antenna Materials Based on Phthalocyanine Stopcocks and Zeolite L

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dc.contributor.authorLópez Duarte, Ismael
dc.contributor.authorLe-Quyenh, Dieu
dc.contributor.authorDolamic, Igor
dc.contributor.authorMartínez Díaz, María Victoria
dc.contributor.authorTorres Cebada, Tomás
dc.contributor.authorCalzaferri, Gion
dc.contributor.authorBrühwiler, Dominik
dc.date.accessioned2024-02-07T16:40:15Z
dc.date.available2024-02-07T16:40:15Z
dc.date.issued2010
dc.description.abstractThe synthesis of stopcocks based on zinc phthalocyanine for selective adsorption at the channel entrances of zeolite L is reported. The introduction of either an inert SiMe3 moiety, an imidazolium cation or a reactive isothiocyanate (NCS) group allows attachment to the channel entrances of zeolite L through van der Waals interactions, electrostatic interactions, or covalent binding, respectively. Stopcocks that rely on van-der-Waals-driven adsorption require careful selection of the solvent used for the deposition onto the zeolite surface to avoid a nonspecific distribution of the molecules. Regarding the design of photonic antenna systems, a stopcock with a cationic tail was found to be the most convenient, based on the observation that efficient energy transfer from molecules located in the zeolite nanochannels is more readily obtained than in the other cases.
dc.description.departmentDepto. de Química en Ciencias Farmacéuticas
dc.description.facultyFac. de Farmacia
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia, Innovación y Universidades (España)
dc.description.sponsorshipMinisterio de Educación, Cultura y Deporte (España)
dc.description.sponsorshipComunidad de Madrid
dc.description.sponsorshipEuropean Commission
dc.description.sponsorshipSwiss National Science Foundation (Suiza)
dc.description.statuspub
dc.identifier.citationLópez‐Duarte I, Le‐Quyenh Dieu, Dolamic I, Martínez‐Díaz MV, Torres T, Calzaferri G, et al. On the Significance of the Anchoring Group in the Design of Antenna Materials Based on Phthalocyanine Stopcocks and Zeolite L. Chemistry A European J 2011;17:1855–62. https://doi.org/10.1002/chem.201002210.
dc.identifier.doi10.1002/chem.201002210
dc.identifier.essn1521-3765
dc.identifier.issn0947-6539
dc.identifier.officialurlhttps://doi.org/10.1002/chem.201002210
dc.identifier.relatedurlhttps://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201002210
dc.identifier.urihttps://hdl.handle.net/20.500.14352/100085
dc.journal.titleChemistry-A European Journal
dc.language.isoeng
dc.publisherWiley
dc.relation.projectIDinfo:eu-repo/grantAgreement/CONSOLIDER-INGENIO2010CDS2007–00010Nanociencia Molecular
dc.relation.projectIDinfo:eu-repo/grantAgreement/PLE2009–0070
dc.relation.projectIDinfo:eu-repo/grantAgreement/MRTN-CT-2006–035533Solar-N-type
dc.relation.projectIDS2009/PPQ/1533/MADRISOLAR-2
dc.relation.projectIDinfo:eu-repo/grantAgreement/200020-117591
dc.relation.projectIDinfo:eu-repo/grantAgreement/Marie-Curie RTNNanomatch
dc.relation.projectIDinfo:eu-repo/grantAgreement/MRTN-CT-2006-035884
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/CTQ2008-00418/BQU
dc.rights.accessRightsrestricted access
dc.subject.keywordEnergy transfer
dc.subject.keywordHost-guest systems
dc.subject.keywordNanochannels
dc.subject.keywordPhthalocyanines
dc.subject.keywordSupramolecular chemistry
dc.subject.keywordZeolites
dc.subject.ucmQuímica
dc.subject.unesco23 Química
dc.titleOn the Significance of the Anchoring Group in the Design of Antenna Materials Based on Phthalocyanine Stopcocks and Zeolite L
dc.typejournal article
dspace.entity.typePublication
relation.isAuthorOfPublicationdec7fdad-6ad2-427a-8113-8d81e6becccb
relation.isAuthorOfPublication.latestForDiscoverydec7fdad-6ad2-427a-8113-8d81e6becccb
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