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Engineering molecular aggregate spectra

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2009

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Wiley-V C H Verlag GmbH
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We show that optical properties of linear molecular aggregates undergo drastic changes when aggregates are deposited on a metal surface. The dipole-dipole interactions of monomers with their images can result in strong re-structuring of both the exciton band and the absorption spectrum, depending on the arrangement of the monomer transition dipoles with respect to the surface.

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©2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. International Conference on Excitonic Processes in Condensed Matter (8. 2008. Kyoto, Japón). A. V. M. acknowledges support from NanoNed, a national nanotechnology program coordinated by the Dutch Ministry of Economic Affairs.

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