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Effect of Incarcerated HF on the Exohedral Chemical Reactivity of HF@C60

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dc.contributor.authorVidal, Sara
dc.contributor.authorIzquierdo, Marta
dc.contributor.authorAlom, Shamim
dc.contributor.authorGarcía-Borrás, Marc
dc.contributor.authorFilippone, Salvatore
dc.contributor.authorOsuna, Silvia
dc.contributor.authorSolà, Miquel
dc.contributor.authorWhitby, Richard J.
dc.contributor.authorMartín León, Nazario
dc.date.accessioned2023-06-17T22:19:00Z
dc.date.available2023-06-17T22:19:00Z
dc.date.issued2017-10-14
dc.description.abstractThe first chemical modification on the brand new endohedral HF@C60 is reported. In particular, the isomerization from optically pure (2S,5S)-cis-pyrrolidino[3,4:1,2][60]fullerene 2b to (2S,5R)-trans-pyrrolidino[3,4:1,2][60]fullerene 2b has been studied and compared with empty C60 (2a) and endohedral H2O@C60 (3). The comparative study shows a kinetic order for the isomerization process of H2O@C60 ˃ HF@C60 ˃ C60, thus confirming the effect of the incarcerated species on the zwitterionic intermediate stability.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipUnión Europea. FP7
dc.description.sponsorshipUnión Europea. H2020
dc.description.sponsorshipMinisterio de Economía y Competitividad (MINECO)
dc.description.sponsorshipComunidad de Madrid
dc.description.sponsorshipCatalan DIUE
dc.description.sponsorshipFEDER
dc.description.sponsorshipEngineering and Physical Sciences Research Council
dc.description.sponsorshipRamon Areces Foundation and S. O. the European Commission for CIG project
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/46345
dc.identifier.doi10.1039/c7cc05987f
dc.identifier.issn1359-7345
dc.identifier.officialurlhttp://pubs.rsc.org/en/content/articlepdf/2017/cc/c7cc05987f
dc.identifier.urihttps://hdl.handle.net/20.500.14352/18364
dc.issue.number80
dc.journal.titleChemical Communications
dc.language.isoeng
dc.page.final11100
dc.page.initial10965
dc.publisherRSC
dc.relation.projectIDCHIRALLCARBON (320441)
dc.relation.projectIDDIREVENZYME (630978)
dc.relation.projectIDNetMoDEzyme (679001)
dc.relation.projectID(project CTQ2014- 52045-R) (CTQ2014-54306-P, CTQ2014-59212-P, and RyC contract RYC-2014-16846 to S. O.)
dc.relation.projectIDFOTOCARBON (S2013/ MIT-2841)
dc.relation.projectID(2014-SGR-931, ICREA Academia 2014 Award to M. S. and XRQTC),
dc.relation.projectID(UNGI10-4E-801)
dc.relation.projectID(EP/1029451, M001962, M001970),(EP/K039466).
dc.relation.projectID(JC IJCI-2014-19320).
dc.rights.accessRightsopen access
dc.subject.cdu547
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco2306 Química Orgánica
dc.titleEffect of Incarcerated HF on the Exohedral Chemical Reactivity of HF@C60
dc.typejournal article
dc.volume.number53
dspace.entity.typePublication
relation.isAuthorOfPublicationb89322ba-6e32-46b6-9008-9d8ac017f23e
relation.isAuthorOfPublicationbbb2c026-daab-46a1-8b57-fa3cf1a7d41a
relation.isAuthorOfPublication.latestForDiscoveryb89322ba-6e32-46b6-9008-9d8ac017f23e

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