Trapping Ag(I) ions by a Pd8 metallacrown molecule to form an unusual nonanuclear AgPd8 cation
| dc.contributor.author | Calleja, Fernando | |
| dc.contributor.author | Cortijo Montes, Miguel | |
| dc.contributor.author | Perles Hernáez, Josefina | |
| dc.contributor.author | Herrero Domínguez, Santiago | |
| dc.contributor.author | Jiménez Aparicio, Reyes | |
| dc.date.accessioned | 2024-01-15T14:33:33Z | |
| dc.date.available | 2024-01-15T14:33:33Z | |
| dc.date.issued | 2019 | |
| dc.description.abstract | The {[Pd(µ-SC6F5)(µ-dppm)Pd](µ-SC6F5)}4 (dppm = methanediylbis(diphenylphosphane)) (Pd8) metallacrown traps Ag(I) cations giving {Ag[Pd(µ3-SC6F5)(µ-dppm)Pd]4(µ-SC6F5)4}(X) (X = SO3CF3− (AgPd8a), SbF6− (AgPd8b) and ClO4− (AgPd8c)) and {Ag[Pd(µ3-SC6F5)(µ-dppm)Pd]4(µ-SC6F5)4}2[Pt(C6F5)4] (AgPd8d). The insertion of silver increases significantly the stability of the cluster that is stable in solution even in the presence of light, because of the macrocyclic effect. | |
| dc.description.department | Depto. de Química Inorgánica | |
| dc.description.faculty | Fac. de Ciencias Químicas | |
| dc.description.refereed | TRUE | |
| dc.description.sponsorship | Ministerio de Economía y ́Competitividad (España) | |
| dc.description.sponsorship | Comunidad de Madrid | |
| dc.description.status | pub | |
| dc.identifier.citation | Calleja, Fernando B., et al. «Trapping Ag(I) Ions by a Pd8 Metallacrown Molecule to Form an Unusual Nonanuclear AgPd8 Cation». Inorganica Chimica Acta, vol. 488, marzo de 2019, pp. 56-61. https://doi.org/10.1016/j.ica.2018.12.049. | |
| dc.identifier.doi | 10.1016/j.ica.2018.12.049 | |
| dc.identifier.issn | 0020-1693 | |
| dc.identifier.officialurl | https://doi.org/10.1016/j.ica.2018.12.049 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14352/93142 | |
| dc.journal.title | Inorganica Chimica Acta | |
| dc.language.iso | eng | |
| dc.page.final | 61 | |
| dc.page.initial | 56 | |
| dc.publisher | Elsevier | |
| dc.relation.projectID | (project CTQ2015-63858-P, MINECO/FEDER) | |
| dc.relation.projectID | (project B2017/BMD-3770-CM) | |
| dc.rights | Attribution 4.0 International | en |
| dc.rights.accessRights | restricted access | |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
| dc.subject.cdu | 546 | |
| dc.subject.keyword | Metallacrown | |
| dc.subject.keyword | Macrocyclic effect | |
| dc.subject.keyword | Palladium clusters | |
| dc.subject.ucm | Química | |
| dc.subject.unesco | 2303 Química Inorgánica | |
| dc.title | Trapping Ag(I) ions by a Pd8 metallacrown molecule to form an unusual nonanuclear AgPd8 cation | |
| dc.type | journal article | |
| dc.type.hasVersion | VoR | |
| dc.volume.number | 488 | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | 132acb8c-4bb3-439a-abd2-60dcda6f71f4 | |
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| relation.isAuthorOfPublication | 0c718374-17f7-4cc9-9345-5936e4fc32ef | |
| relation.isAuthorOfPublication.latestForDiscovery | 132acb8c-4bb3-439a-abd2-60dcda6f71f4 |
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