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Robust large area molecular junctions of selfassembled monolayers of a model helical paddlewheel complex

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dc.contributor.authorColoma Manjón-Cabeza, Isabel
dc.contributor.authorBuffeteau, Thierry
dc.contributor.authorPecastaings, Gilles
dc.contributor.authorHerrero Domínguez, Santiago
dc.contributor.authorHillard, Elizabeth
dc.contributor.authorRosa, Patrick
dc.contributor.authorCortijo Montes, Miguel
dc.contributor.authorGonidec, Mathieu
dc.date.accessioned2025-04-04T08:21:43Z
dc.date.available2025-04-04T08:21:43Z
dc.date.issued2025
dc.descriptionThe author acknowledge support from the Universidad Complutense de Madrid (GRFN32/23, GRFN24/24 and project PR3/23-30828), the France 2030 government investment plan managed by the French National Research Agency under grant reference PEPR SPIN – SPINMAT ANR-22-EXSP-0007, the Imperial College – CNRS joint PhD program, Quantum Matter Bordeaux, the MaelStroM project (CNRS MITI program), the National Research Agency project AnaCrU-CISS (ANR-23-CE09-0026) and the GPR Light project LIGHT-057-ChiroSurf. I.C. acknowledges predoctoral grant from the Complutense University of Madrid and Banco Santander (CT82/20-CT83/20). The authors warmly thank J.P. Salvetat of the Placamat service unit (France) for the ToF-SIMS measurements and Stéphane Toulin for assistance with the open data repository. Computer time for the theoretical calculation was provided by the computing facilities MCIA (Mésocentre de Calcul Intensif Aquitain) of the Université de Bordeaux.
dc.description.abstractWe report the preparation of a helical complex and its study in molecular junctions. We show that the SAMs of this racemic compound present an electrically robust behaviour which will pave the way for future studies of the CISS effect with analogous enantiopure compounds.
dc.description.departmentDepto. de Química Inorgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipUniversidad Complutense de Madrid
dc.description.sponsorshipAgence Nationale de la Recherche (France)
dc.description.sponsorshipImperial College
dc.description.sponsorshipBanco Santander
dc.description.sponsorshipUniversité de Bordeaux
dc.description.statuspub
dc.identifier.citationColoma, I.; Buffeteau, T.; Pecastaings, G.; Herrero, S.; Hillard, E.; Rosa, P.; Cortijo, M.; Gonidec, M. Robust Large Area Molecular Junctions of Self-Assembled Monolayers of a Model Helical Paddlewheel Complex. Nanoscale 2025, 10.1039.D5NR00050E. https://doi.org/10.1039/D5NR00050E.
dc.identifier.doi10.1039/D5NR00050E
dc.identifier.essn2040-3372
dc.identifier.issn2040-3364
dc.identifier.officialurlhttps://doi.org/10.1039/D5NR00050E
dc.identifier.relatedurlhttps://pubs.rsc.org/en/content/articlelanding/2025/nr/d5nr00050e
dc.identifier.urihttps://hdl.handle.net/20.500.14352/119232
dc.journal.titleNanoscale
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.rightsAttribution 4.0 Internationalen
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subject.cdu54
dc.subject.ucmQuímica
dc.subject.unesco23 Química
dc.titleRobust large area molecular junctions of selfassembled monolayers of a model helical paddlewheel complex
dc.typejournal article
dc.type.hasVersionAM
dspace.entity.typePublication
relation.isAuthorOfPublicationa10f3452-00da-4212-922b-76f48b7b8dbf
relation.isAuthorOfPublication59924d8b-089e-42db-b835-600c5cee5487
relation.isAuthorOfPublication132acb8c-4bb3-439a-abd2-60dcda6f71f4
relation.isAuthorOfPublication.latestForDiscoverya10f3452-00da-4212-922b-76f48b7b8dbf

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